Linear viscoelasticity of colloidal hard sphere suspensions near the glass transition.

The frequency-dependent viscoelastic shear modulus of concentrated suspensions of colloidal hard spheres is shown to be strongly modified as the volume fraction approaches the glass transition. The elastic or storage component, G0, becomes larger than the viscous or loss component, G00. The frequency dependence of G0 develops a plateau while that of G00 develops a minimum. We propose a physical model to account for these data, using a description of the glasslike behavior based on mode-coupling theory, and a description of the high-frequency behavior based on hydrodynamic flow calculations.